With no discernable pattern, i.e. gear ratios, pedal loading my chain keeps on coming off while shifting from the 53-tooth ring to the 39 ring. I am running Ultegra throughout and have a 12-25 on the rear.The front deraliar is adjusted so that is now just rubs the chain in the 39/25 ratio, still the problem continues. Every time the chain comes off is takes another gouge out of my Carbon frame and it’s pissing me off. Any ideas??