I work at a pro bike shop in Dallas, TX, and I recently heard a few pros going at it over this exact same issue.
Apparently, due to the TdF minimum weight requirements, weight is a non-issue. They will both have no problem being right at the minimum because of Cervelo's reputation for prioritizing weight and cutting unnecessary material. Further, CSC was riding the new carbon prototype soloists rather than the aluminum ones last TdF in '05. Since the soloist is more aerodynamic and known for being slightly stiffer due to its extremely compact geometry, most of the team chose to stick with the Soloist rather than opting for a R2.5.
That said, the new carbon Soloist does not come out for another couple of months (I have not seen any in the shop, nor has our Cervelo distributor seen any yet). At this point, the advantages of carbon, generally, so far overwhelm the soloist's aerodynamics that I have seen very few people purchasing the Soloist. This is most likely why Cervelo is creating a carbon version of the Soloist.
Okay - all of that jabber aside - I got to witness a USCF Elite cycling coach hashing it out with some of the local pro racers over his Soloist. As a coach, he's been riding the Soloist line since 2001. He works with pros using power output and aero efficiency to increase general awareness and having more than your legs in the race. He rides a good three hundred miles a week on his aluminum Soloist, and can honestly say that it is not a comfortable ride. Riding with his clients, he feels he needs that much "power" and "stiffness" to keep up, versus using a "cushier" frame like the R2.5.
One of the pros he works with uses an R2.5 because he has an amazing heart but lacks the big fast twitch muscle of a sprinter. He needs something as lightweight as possible that will give him a little bit more give on long rides while still maintaining Cervelo's stiff precedent set by the Soloist.
If I were to pick between the two, I would choose the R2.5, but then I do not race every weekend, nor is racing my #1 concern right now.
Just my two and a half cents.