Yes, latex tubes decrease rolling resistance. I'd have to look at the data to see if it works out around 10% or not, but it is substantial and measurable with a commercial power meter. I don't believe it's the weight of the latex vs. butyl as much as the flexibility and suppleness of the latex reducing hysteresis losses when it naturally bends and flexes at the ever changing contact patch with the road.
The down sides to latex vs. butyl are that latex leaks air ever so slightly so tires will lose 5 to 10 psi or more overnight so you want to pump up latex tires before every ride. Latex tubes are also very prone to getting pinched under the tire beads during installation so you want to be extra careful installing them to make sure they don't burst as you initially inflate them. For that reason I don't carry latex spare tubes as it's more likely to do a slightly sloppy install while standing at the roadside with a flat so my spares are butyl even when I'm riding latex. Latex tubes also have an insidious tendency to creep into any possible opening in the rim strip which can result in a blowout while riding. So if you use latex tubes make sure your spoke holes are completely covered with rim strip in good condition.
All that makes latex tubes sound like a huge hassle, but they're really not. You have to pay a bit closer attention while mounting your tires to make absolutely sure you haven't pinched any of the very thin latex under a tire bead and you have to keep your equipment in good condition which includes good rimstrip and pumping your tires regularly but they do roll very fast. FWIW, I only race on latex and ride day to day on butyl tubes.
I like Vredstein, Vittoria, and Michelin latex tubes but there are probably others out there.
-Dave
[edit] looks like Alienator got to the line first....so yeah, what he said ^^^^