Originally Posted by danfoz
Also possibly less than ideal things happening to the CF rim walls vs typical alloy rim walls as they heat up on a fast decent?
Friction?
Originally Posted by alienator
Danfoz is right that higher pressure will result in higher temps in the air inside a tube, at least that's what was found from Sr. Boltzmann's distribution.
Increasing gas temperature increases gas pressure when the gas is in an enclosed space (
Gay-Lussac's Law i.e. Amontons' Law), but I don't think it works the other way around.
As far as I know, increasing the molar density should buffer against changes in air temperature. A larger amount of gas will require more kinetic energy to achieve an equal rise in temperature.
n/V = P/RT
n/V is molar density.
P is pressure
T is temperature
R is a mathematical constant
If over-inflating your tubes somehow leads to more friction, that
miiight do it. I don't know. Ask a chemist and/or physicist. However, per the calculations below, you would have to raise the temperature quite a bit to see a significant increase in psi.
Ratio of temperature increase to pressure increase:
PV = nRT
One form of the calculation assigns R=0.08206, and uses the units: moles, atmospheres, Liters, and Kelvins.
Moles and Liters (n & V) will be held constant.
Conversion factors:
1 atm = 14.7 psi
1 K ∠1 C°
1 K ∠1.8 F°
TR = P
T x 0.08206 = P
An increase of 0.08206 atmopsheres, or 1.2 psi, per degree Celsius.
If we're talking Fahrenheit.
1.2 ÷ 1.8 = 0.67
That's 0.67 psi per degree Fahrenheit.
So the corresponding change in pressure shouldn't be a problem unless you are increasing the temperature by something like 15 degrees Fahrenheit.
Just don't fill your tube with air that is significantly warmer or cooler than what it will be exposed to during your ride. So don't fill it inside your house, and don't fill it in the morning or at night while the temperature is low.
That reminds me. My most recent purchase was a Silca floor pump.