Sorry to have a spray BRettM but most of your answers so far have been
nothing short of woeful.
It doesn't matter what you do, if you have two dissimilar metals in
electrical contact, one of them will corrode. HUmbug is right - as long as
you eliminate that coupling, you are OK to go. Sure, the degree of corrosion
will change depending on the electrolytic potentials of the two metals. Bang
some grease on there and make sure there is no place for the water to pool.
You should be ok. Note: some greases contain lithium, which will make your
grease conductive --> bad.
Quoted message said:True, and if you couple pure titanium and pure aluminium in a
saline environment then the aluminium will corrode rapidly.
But add a little nickel to the aluminium and the couple will
be almost inert. most aluminium alloys used in bikes include nickel.
No they do not. The Al-Mg-Si (6xxx series) do not contain Nickel (6061 is
1.0 Mg, 0.7 Si, 0.3 Cu, trace Ti), nor do the Al-Zn (7xxx) series (7005 is
4.6 Zn, 1.4 Mg, 0.5 Mn, 0.1 Cr,0.1 Zr, 0.03 Ti) which are the most common of
aluminium alloys used in frames. In fact, Nickel has a maximum solid
solubility of 0.04 wt% in Al. You are correct in saying that Nickel improves
corrosion resistance, but it's influence would be minor. The addition of
titanium is more common, but it is added for grain refinement (strength
increases) rather than for improved corrosion resistance. Chromium is often
added to counteract the negative effects that copper has on corrosion
resistance.
Quoted message said:Ti-Al or Ti-Al-Ni/Nb alloys are commonly used for
surgical procedures (pins/plates etc) because they are stable
within a saline environment.
I think you will find that Ti-Al-V are more common. Yes they are more stable
but they also do not suffer from stress corrosion cracking (c.f. 3xx series
stainless steels). The lower Young's modulus, E (~120GPa), of titanium
compared with steel (207 GPa) also allows for improved tissue integration
(e.g. bone growing into the surface of the implant).
Quoted message said:
There should also be little concern in blending stainless
steel with titanium but it will depend on the admixtures.
"blending stainless with titanium" . See point above about dissimilar
metals.
"admixtures". ever heard of alloying composition?
The biggest issue with titanium is fatigue strength. As I have mentioned on
here before, localised oxidation due to fretting reduces the fatigue life of
titanium massively. Keep those titanium bits well greased.
Anyway, that's my rant
Jimbo