Chris Gerhard said:Wow I learn something new every day. CO2 permeates through the rubber
despite being a larger molecule.
CO2 does escape from the inner tube. Otherwise it would be a wonder gas for
cyclists and used routiney by many of us instead of just for emergencies.
Not having to top your tyres up would be convenient! You'd never have to
pump your tyres up exccept after a puncture or tyre replacement. But sadly,
that is not the case.
Since I'm not a scientist I had forgotton how CO2 escapes from tyres. I
just knew that it did - and faster than air does. It's a well-known fact,
actually. I don't really understand anything. I just know a few things :-)
A quick Google finds some good detail:
QUOTE - - - - - - - - - - - - - -
It's not porosity that causes latex tubes to lose air.
About 80% of the atmosphere is N2, 20% is 02, and a smidgen is CO2.
(Plus milli-smidgens of a few other rare gases.)
These gases are soluble in both butyl and latex rubber:
http://www.madsci.org/posts/archives/may98/895552329.Ch.r.html
As that short article explains, CO2 is about 15 times as chemically
soluble in rubber as N2. That's why tubes inflated with CO2 cartridges
lose "air" so quickly compared to tubes inflated with 80% N2 from a
hand pump.
Just as CO2 is much more soluble than N2, latex is much more
chemically soluble than butyl. So expensive latex tubes lose gases
much more quickly than ordinary butyl tubes. It's not a mechanical
matter of "pores" being larger in latex--it's a chemical process in
which latex is more reactive.
In the process, the gases are attracted to the rubber and are drawn
into it, between its atoms. There's less pressure on the other side of
the tube, so that's where the gas atoms come out of solution.
Eventually, the tire goes flat.
This is why party balloons filled with helium last longer when they
have that shiny metal foil coating. Neither the rubber nor the metal
have "pores" like the pores in our skin, and the size of the gas atoms
doesn't matter. It's just that the gases are chemically soluble in
rubber, but not in metal.
- Carl Fogel, rec.bicycles.tech, http://tinyurl.com/2do6uc
END QUOTE - - - - - - - -
I believe that porosity is relevant to tyres inflated with air, though. The
thickness of the tube and tyre is relevant to air and CO2 anyway, regardless
of porosity, so my "bottom lines" still stand.
As well as the deflation issue, CO2 is also quite corrosive to rubber and
some synthetics and can "rot" it. I'm not really sure if this is a
practical concern for inner tubes. If it is, it's another reason to replace
with air sooner rather than later.
~PB