cyclist101 may have said:Werehatrack said:Quoted message said:I *don't* recommend gasoline for cleaning chains. I use diesel, which isn't combustible. I
haven't tried kerosene.
Diesel has a flash point that's higher than gasoline, and a vapor pressure that's lower, but if
it's hit by a spark, it will most certainly ignite.
Most certainly not. Take some diesel at room temperature and throw a match in it. The match will be
extinguished.
This varies with conditions; on a hot summer day, you most certainly can light diesel by dropping
a match into an open shallow pan containing it. The probability increases dramatically if there's
a rag or brush present to increase the surface area, which speeds evaporation and contributes to
the formation of a vapor pool. If this sounds like the typical scenario involved in cleaning
parts, it should.
I had the unpleaseant duty of having to extinguish such a fire once, and of transporting the
neighbor who had been badly burned while cleaning motorcycle parts in diesel. A conversation with a
fire marshal a few months later was, shall we say, illuminating. Mineral spirits *is* safer; to see
the difference, try soaking equal quantities of charcoal briquets with equal amounts of diesel and
spirits, and then lighting them; unless it's a cold day, you'll find that the diesel lights easier
and burns far more enthusiastically than the mineral spirits.
I am aware that farmers have used diesel for parts washing solvent for a long time. They also are
famous for charging their AC systems with propane. It works, but that neither makes it safe nor a
good idea.
Quoted message said:Quoted message said:Kerosene and mineral spirits are both far safer to use.
Mineral spirits is far more combustible than diesel.
The paint-thinner grade of mineral spirits that I've been picking up won't readily flash at common
temperatures unless wicked. The diesel that I've worked with for years will flash at common *summer*
temps with just a source of ignition, if there is enough of it present to form a vapor pool of the
needed size...which is much smaller than you might think. There are lots of heavy equipment
mechanics who can tell you this first hand. Mineral spirits vapor, on the other hand, tends to
disperse more readily, thus reducing the buildup of flashable vapor. (Even with mineral spirits,
though, if the ambient temp is high enough and the venitlation poor enough, the vapor pressure can
rise to the point where it's ignitable.)
Quoted message said:Quoted message said:Gasoline is so readily ignited, and so volatile, that it's *really* hazardous, since it can be
ignited by someone dropping a lit cigarette as much as ten to twenty feet away.
Another good reason not to smoke.
Agreed!
Quoted message said:Quoted message said:The current formulations of gasoline also contain fractions that are mildly carcinogenic,
although at least in 49 states in the US, there's no tetraethyl lead anymore.
Even so, I'd be more immediately concerned with flash fires in or near my garage (which is attached
to my house, in which my family reside) than future cancer risks.
Also agreed. This is enough of a concern that most US building codes now mandate that a gas-fired
water heater must be installed with a support structure that lifts the unit well above floor
level if it's located in a garage or exterior storage room. This is entirely because of the fact
that too many people will keep a lawn mower or improperly sealed gas can in the same room, and
gasoline vapors from that receptacle may disperse poorly, forming a gradually deepening layer of
flammable fumes at floor level. When the layer reaches the pilot light of the water heater,
things get loud and hot.
By the way, there's a not-really-safety reason to avoid using diesel as a cleaning agent; it has a
very pungent smell that will signal to all and sundry that it's present, and the aroma can cause
neighborhood busybodies to call fire department and other inspectors to have a look-see...and in
many areas, using non-approved solvents for parts cleaner will net you a citation of some sort.
Mineral spirits evaporates with less smell, doesn't linger long, and generally won't get you into
trouble with the regulatory gestapo.
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